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<title>Localized surface plasmon</title>
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<h1 id="firstHeading" class="firstHeading mw-first-heading">
<span id="openzim-page-title" class="mw-page-title-main"><span class="mw-page-title-main">Localized surface plasmon</span></span>
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<p>A <b>localized surface plasmon</b> (<b>LSP</b>) is the result of the confinement of a <a href="Surface_plasmon" title="Surface plasmon">surface plasmon</a> in a <a href="Nanoparticle" title="Nanoparticle">nanoparticle</a> of size comparable to or smaller than the wavelength of <a href="Light" title="Light">light</a> used to excite the <a href="Plasmon" title="Plasmon">plasmon</a>. When a small spherical metallic nanoparticle is irradiated by light, the oscillating electric field causes the conduction electrons to oscillate coherently. When the electron cloud is displaced relative to its original position, a restoring force arises from Coulombic attraction between electrons and nuclei. This force causes the electron cloud to oscillate. The oscillation frequency is determined by the density of electrons, the effective electron mass, and the size and shape of the charge distribution.<sup id="cite_ref-:0_1-0" class="reference"><a href="#cite_note-:0-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> The LSP has two important effects: <a href="Electric_field" title="Electric field">electric fields</a> near the particle's surface are greatly enhanced and the particle's optical absorption has a maximum at the <a href="Plasmon" title="Plasmon">plasmon</a> <a href="Resonant_frequency" class="mw-redirect" title="Resonant frequency">resonant frequency</a>. <a href="Surface_plasmon_resonance" title="Surface plasmon resonance">Surface plasmon resonance</a> can also be tuned based on the shape of the nanoparticle.<sup id="cite_ref-:0_1-1" class="reference"><a href="#cite_note-:0-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> The plasmon frequency can be related to the metal dielectric constant.<sup id="cite_ref-:0_1-2" class="reference"><a href="#cite_note-:0-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> The enhancement falls off quickly with distance from the surface and, for <a href="Noble_metal" title="Noble metal">noble metal</a> nanoparticles, the resonance occurs at visible wavelengths.<sup id="cite_ref-:1_2-0" class="reference"><a href="#cite_note-:1-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup> Localized surface plasmon resonance creates brilliant colors in metal colloidal solutions.<sup id="cite_ref-Skrabalak_2182–2190_3-0" class="reference"><a href="#cite_note-Skrabalak_2182–2190-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup>
</p><p>For metals like silver and gold, the oscillation frequency is also affected by the electrons in d-orbitals. Silver is a popular choice in plasmonics, which studies the effect of coupling light to charges, because it can support a surface plasmon over a wide range of wavelengths (300-1200&nbsp;nm), and its peak absorption wavelength is easily changed.<sup id="cite_ref-:1_2-1" class="reference"><a href="#cite_note-:1-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup> For instance, the peak absorption wavelength of triangular silver nanoparticles was altered by changing the corner sharpness of the triangles. It underwent a blue-shift as corner sharpness of the triangles decreased.<sup id="cite_ref-4" class="reference"><a href="#cite_note-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> Additionally, peak absorption wavelength underwent a red-shift as a larger amount of HAuCl<sub>4</sub> was added and porosity of the particles increased.<sup id="cite_ref-Skrabalak_2182–2190_3-1" class="reference"><a href="#cite_note-Skrabalak_2182–2190-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup> For semiconductor nanoparticles, the maximum optical absorption is often in the near-infrared and mid-infrared region.<sup id="cite_ref-5" class="reference"><a href="#cite_note-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-6" class="reference"><a href="#cite_note-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup>
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<div class="mw-heading mw-heading2"><h2 id="Propagating_surface_plasmons">Propagating surface plasmons</h2></div>
<p>Localized surface <a href="Plasmon" title="Plasmon">plasmons</a> are distinct from propagating surface plasmons. In localized surface plasmons, the electron cloud oscillates collectively. In propagating surface plasmons, the surface plasmon propagates back and forth between the ends of the structure. Propagating surface plasmons also need to have at least one dimension that is close to or longer than the <a href="Wavelength" title="Wavelength">wavelength</a> of <a href="Incident_light" class="mw-redirect" title="Incident light">incident light</a>. The waves created in propagating surface plasmons can also be tuned by controlling the geometry of the metal <a href="Nanostructure" title="Nanostructure">nanostructure</a>.<sup id="cite_ref-:1_2-2" class="reference"><a href="#cite_note-:1-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup>
</p>
<div class="mw-heading mw-heading2"><h2 id="Characterization_and_study">Characterization and study</h2></div>
<p>A goal of <a href="Plasmonics" title="Plasmonics">plasmonics</a> is to understand and manipulate surface plasmons at the nano-scale, so characterization of surface plasmons is important. Some techniques frequently used to characterize surface plasmons are <a href="Dark-field_microscopy" title="Dark-field microscopy">dark-field microscopy</a>, <a href="UV_Vis" class="mw-redirect" title="UV Vis">UV-vis-NIR spectroscopy</a>, and <a href="Surface-enhanced_Raman_scattering" class="mw-redirect" title="Surface-enhanced Raman scattering">surface-enhanced Raman scattering</a> (SERS).<sup id="cite_ref-:1_2-3" class="reference"><a href="#cite_note-:1-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup> With dark-field microscopy, it is possible to monitor the spectrum of an individual metal nanostructure as the incident light polarization, wavelength, or variations in the <a href="Dielectric" title="Dielectric">dielectric</a> environment is changed.<sup id="cite_ref-7" class="reference"><a href="#cite_note-7"><span class="cite-bracket">[</span>7<span class="cite-bracket">]</span></a></sup>
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<div class="mw-heading mw-heading2"><h2 id="Applications">Applications</h2></div>

<p>The plasmon <a href="Resonant_frequency" class="mw-redirect" title="Resonant frequency">resonant frequency</a> is highly sensitive to the <a href="Refractive_index" title="Refractive index">refractive index</a> of the environment; a change in refractive index results in a shift in the resonant frequency. As the resonant frequency is easy to measure, this allows LSP nanoparticles to be used for <a href="Nanoscopic_scale" class="mw-redirect" title="Nanoscopic scale">nanoscale</a> sensing applications.<sup id="cite_ref-8" class="reference"><a href="#cite_note-8"><span class="cite-bracket">[</span>8<span class="cite-bracket">]</span></a></sup> Also, nanoparticles exhibiting strong LSP properties, such as gold <a href="Nanorod" title="Nanorod">nanorods</a> and <a href="Gold_nanocage" title="Gold nanocage">gold nanocages</a>, could enhance the signal in surface plasmon resonance sensing.<sup id="cite_ref-9" class="reference"><a href="#cite_note-9"><span class="cite-bracket">[</span>9<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-10" class="reference"><a href="#cite_note-10"><span class="cite-bracket">[</span>10<span class="cite-bracket">]</span></a></sup> Nanostructures exhibiting LSP resonances are used to enhance signals in modern <a href="Analytical_technique" class="mw-redirect" title="Analytical technique">analytical techniques</a> based on <a href="Spectroscopy" title="Spectroscopy">spectroscopy</a>. Other applications that rely on efficient light to heat generation in the nanoscale are <a href="Heat-assisted_magnetic_recording" title="Heat-assisted magnetic recording">heat-assisted magnetic recording</a> (HAMR), <a href="Photothermal_therapy#Gold_NanoRods_(AuNR)" title="Photothermal therapy">photothermal cancer therapy</a>, and thermophotovoltaics.<sup id="cite_ref-11" class="reference"><a href="#cite_note-11"><span class="cite-bracket">[</span>11<span class="cite-bracket">]</span></a></sup> So far, high-efficiency applications using plasmonics have not been realized due to the high <a href="Ohmic_loss" class="mw-redirect" title="Ohmic loss">Ohmic losses</a> inside metals especially in the <a href="Optical_spectrum" class="mw-redirect" title="Optical spectrum">optical spectral</a> range (visible and <a href="Near_infrared" class="mw-redirect" title="Near infrared">NIR</a>).<sup id="cite_ref-12" class="reference"><a href="#cite_note-12"><span class="cite-bracket">[</span>12<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-13" class="reference"><a href="#cite_note-13"><span class="cite-bracket">[</span>13<span class="cite-bracket">]</span></a></sup>
</p><p>Additionally, surface plasmons have been used to create <a href="Super_lens" class="mw-redirect" title="Super lens">super lenses</a>, <a href="Cloaking_device" title="Cloaking device">invisibility cloaks</a>, and to improve <a href="Quantum_computing" title="Quantum computing">quantum computing</a>.<sup id="cite_ref-14" class="reference"><a href="#cite_note-14"><span class="cite-bracket">[</span>14<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-15" class="reference"><a href="#cite_note-15"><span class="cite-bracket">[</span>15<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-16" class="reference"><a href="#cite_note-16"><span class="cite-bracket">[</span>16<span class="cite-bracket">]</span></a></sup> Another interesting area of research in plasmonics is the ability to turn plasmons "on" and "off" via modification of another molecule. The ability to turn plasmons on and off has important consequences for increasing sensitivity in detection methods.<sup id="cite_ref-:1_2-4" class="reference"><a href="#cite_note-:1-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup> Recently, a supramolecular <a href="Chromophore" title="Chromophore">chromophore</a> was coupled with a metal nanostructure. This interaction changed the localized surface plasmon resonance properties of the silver nanostructure by increasing the absorption intensity.<sup id="cite_ref-17" class="reference"><a href="#cite_note-17"><span class="cite-bracket">[</span>17<span class="cite-bracket">]</span></a></sup> &nbsp;
</p>
<div class="mw-heading mw-heading2"><h2 id="See_also">See also</h2></div>
<ul><li><a href="Surface_plasmon_resonance" title="Surface plasmon resonance">Surface plasmon resonance</a></li>
<li><a href="Surface-enhanced_Raman_spectroscopy" title="Surface-enhanced Raman spectroscopy">Surface-enhanced Raman spectroscopy</a></li>
<li><a href="Nanoparticle" title="Nanoparticle">Nanoparticle</a></li>
<li><a href="Tip-enhanced_Raman_spectroscopy" title="Tip-enhanced Raman spectroscopy">Tip-enhanced Raman spectroscopy</a></li></ul>
<div class="mw-heading mw-heading2"><h2 id="References">References</h2></div>
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